Search results for "Born-Oppenheimer approximation"
showing 3 items of 3 documents
Théorie des spectres rovibroniques des molécules octaédriques : Hamiltonien et moments de transition
2002
This thesis is devoted to the treatment of rovibronic couplings of octahedral species for which the Born-Oppenheimer approximation is broken down. By using the octahedral formalism, a full effective rovibronic model is extended from works about molecules in a non-degenerate electronic state. This effective model is dedicated to molecules with an odd or an even number of electrons and it has been successfully applied to V(CO)6 and ReF6. For both of them we have four interacting vibronic sublevels attributed to a dynamical Jahn-Teller effect and giving rise to very complicated spectra. This model is validated by the overall agreement between predicted and observed band profiles. Moreover, an …
Few-body insights of multiquark exotic hadrons
2018
In this contribution we discuss the adequate treatment of the $4-$ and $5-$body dynamics within a constituent quark framework. We stress that the variational and Born-Oppenheimer approximations give energies rather close to the exact ones, while the diquark approximation might be rather misleading. Hall-Post inequalities provide very useful lower bounds that exclude possible stable states for some mass ratios and color wave functions.
Few-body quark dynamics for doubly heavy baryons and tetraquarks
2018
We discuss the adequate treatment of the 3- and 4-body dynamics for the quark model picture of double-charm baryons and tetraquarks. We stress that the variational and Born-Oppenheimer approximations give energies very close to the exact ones, while the diquark approximation might be rather misleading. The Hall-Post inequalities also provide very useful lower bounds that exclude the possibility of stable tetraquarks for some mass ratios and some color wave functions.